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A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of [Ru(dppe)Cp*]2(mu-C14) and [Co3(mu-dppm)(CO)7]2(mu3:mu3-C16). | LitMetric
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A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of [Ru(dppe)Cp*]2(mu-C14) and [Co3(mu-dppm)(CO)7]2(mu3:mu3-C16).

Alla B Antonova Michael I Bruce Benjamin G Ellis Maryka Gaudio Paul A Humphrey Martyn Jevric Giovanni Melino Brian K Nicholson Gary J Perkins Brian W Skelton Bronwin Stapleton Allan H White Natasha N Zaitseva

Chem Commun (Camb)

Department of Chemistry, University of Adelaide, Adelaide, South Australia 5005, Australia.

Published: April 2004

Elimination of AuX(PR3)(X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)- or C(sp2)-X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by C(n) chains (n up to 16).

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http://dx.doi.org/10.1039/b315854nDOI Listing

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