We report the preparation of the first real bis(allenylidene) metal complex trans-[Ph2C=C=C=Ru=C=C=CPh2(dppe)2]2+, and its one electron reduction that gives a stable radical with the unpaired electron delocalized over both trans carbon-rich chains linked by the ruthenium atom, on the basis of spectroscopic and DFT, QM(DFT)/MM computational studies.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja049631+ | DOI Listing |
Publication Analysis
Top Keywords
metal complex
8
trans carbon-rich
8
carbon-rich chains
8
bis-allenylidene metal
4
complex unique
4
unique radical
4
radical delocalization
4
delocalization electron
4
electron trans
4
chains report
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!