p-Tolylsulfinyl amides: reagents for facile electrophilic functionalization of olefins.

J Org Chem

Davenport Building, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada.

Published: April 2004

A variety of olefins were found to react with sulfinyl amides in the presence of POCl(3) to give beta-chlorosulfides and beta-hydroxysulfides in good yields. In the absence of nucleophiles, p-tolylsulfinyl amides were found to react with olefins with the formation of allylsulfoxides.

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http://dx.doi.org/10.1021/jo035518aDOI Listing

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