Photodegradation of pentachlorophenol (PCP) in aquatic surface microlayer (SM) was examined under natural sunlight. SM samples were collected using a glass plate, along with corresponding subsurface waters. PCP was added to samples of the SM and subsurface water. When all samples were exposed to the same natural sunlight conditions, the first order photodegradation rates of PCP in the SM water samples were different from those of PCP in corresponding subsurface water samples. The difference was correlated with the enrichment of dissolved organic carbon (DOC) in SM compared to the corresponding subsurface waters. Enhanced photodegradation in SM may be due to increased abundance of photoreactants related to the UV-absorbing properties of dissolved organic materials in the SM as the result of photo-induced reactions. Effects of environmental factors, pH and salinity, on photodegradation process of PCP in SM were also evaluated.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1081/pfc-120027439 | DOI Listing |
J Biophotonics
December 2024
Department of Biomedical Engineering, University of Arkansas, Fayetteville, Arkansas, USA.
We report on the development of a multimodal spectroscopy system, combining diffuse reflectance spectroscopy (DRS) and spatially offset Raman spectroscopy (SORS). A fiber optic probe was designed with spatially offset source-detector fibers to collect subsurface measurements for each modality, as well as ball lens-coupled fibers for superficial measurements. The system acquires DRS, zero-offset Raman spectroscopy (RS) and SORS with good signal-to-noise ratio.
View Article and Find Full Text PDFInt J Legal Med
December 2024
Department of Medical Biology, Section Clinical Anatomy and Embryology, AmsterdamUMC, Location Academic Medical Centre, Meibergdreef 9, Amsterdam, AZ, 1105, The Netherlands.
Forensic taphonomy is the study of postmortem changes of human remains for the purpose of answering legal investigative questions. Many variables can affect the pattern and rate of decomposition of remains, posing challenges for taphonomic studies and estimation of the postmortem interval. Given the gap in knowledge regarding the suitability of using frozen remains to extrapolate conclusions to fresh material, investigating the effects of freeze-thaw cycles followed by burial on human remains is vital for forensic practice and taphonomic research.
View Article and Find Full Text PDFPLoS One
December 2024
School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou, China.
The microstructure, hardness, residual stress, and friction and wear properties of 25CrNi2MoV steel with different particle diameters during shot peening strengthening were studied. Studies have shown that a grain refinement layer appeared on the surface of the material after shot peening. The shot peening intensity increased with increasing particle diameter; a greater shot peening intensity corresponded to a greater surface hardness of the material, the maximum hardness was 592 HV0.
View Article and Find Full Text PDFMar Pollut Bull
December 2024
Institute of Marine Research, Acoustics and Observation Methodologies Research Group, Austevoll Research Station, Sauganeset 16, N-5392 Storebø, Norway. Electronic address:
Controlled source electromagnetics (CSEM) uses electromagnetic fields (EMF) to detect oil reservoirs. Atlantic haddock, Melanogrammus aeglefinus, is a commercially important demersal fish species that can potentially be impacted by such surveys due to potential overlap with egg distribution. In this study, haddock eggs were exposed to EMF, replicating CSEM survey conditions in a laboratory.
View Article and Find Full Text PDFWater Sci Technol
November 2024
Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, SE-971 87 Luleå, Sweden.
Stormwater is recognised as a vector for microplastics (MPs), including tyre wear particles (TWPs) from land-based sources to receiving waterbodies. Before reaching the waterbodies, the stormwater may be treated. In this study, sediments from six treatment facilities (five retention ponds and a subsurface sedimentation tank) were analysed to understand MP occurrence, concentrations, sizes, polymer types and distribution between inlet and outlet.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!