Bis(N,N-di-n-butyldithiocarbamato-kappa2S,S')(1,10-phenanthroline-kappa2N,N')zinc(II) ethanol hemisolvate, [Zn(C9H18NS2)2(C12H8N2)].0.5C2H6O, (I), and bis(N,N-di-n-hexyldithiocarbamato-kappa2S,S')bis(1,10-phenanthroline-kappa2N,N')calcium(II), [Ca(C13H26NS2)2(C12H8N2)2], (II), are mixed-ligand complexes. In the first compound, the Zn atom has a distorted octahedral coordination, while in the second compound, the Ca atom is eight-coordinate, with four S and four N atoms forming a highly distorted cube.
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