Phenyl-substituted cyclopentadienes are proved to form phenylated pyrylium cations in the presence of silver(I) perchlorate by insertion of an oxygen atom into the cyclopentadiene-ring. Three phenylated pyrylium compounds, [(Ph(5)C(5)O(+))(ClO(4)(-))](2)(CH(2)Cl(2)) (1), Ag(ClO(4))(H(2)O)(Ph(4)HC(5)O(+)) (ClO(4)(-)) (2), and (Ph(3)H(2)C(5)O(+))(ClO(4)(-)) (3) have been synthesized and characterized. A possible reaction pathway and formation mechanism of the pyrylium cation are proposed and discussed.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jo030243k | DOI Listing |
Publication Analysis
Top Keywords
phenyl-substituted cyclopentadienes
8
pyrylium cations
8
phenylated pyrylium
8
conversion phenyl-substituted
4
pyrylium
4
cyclopentadienes pyrylium
4
cations phenyl-substituted
4
cyclopentadienes proved
4
proved form
4
form phenylated
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!