Relaxation dynamics of langmuir polymer films: a power-law analysis.

Phys Rev Lett

Departamento de Química Física I, Facultad de Química, Universidad Complutense, Ciudad Universitaria s/n, E28040 Madrid, Spain.

Published: December 2003

We report an experimental study on the mechanical relaxation of Langmuir films of a flexible polymer: polyvinylacetate, a good example of a two-dimensional polymeric system at good-solvent conditions. This study allows us to explore the dependence of the relaxation times and the surface viscosity on the concentration. In the semidilute regime, both dynamical properties follow well-defined power laws, which are in quantitative agreement with 2D reptation.

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http://dx.doi.org/10.1103/PhysRevLett.91.268302DOI Listing

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