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Determination of triazine pesticides and related compounds in environmental water by liquid chromatography-mass spectrometry. | LitMetric

AI Article Synopsis

  • A new method using liquid chromatography-electrospray ionization mass spectrometry (LC/ESI/MS) has been developed to detect 5 triazine herbicides and 12 of their degradation products in environmental water samples.
  • The extraction of pesticides from water involved two types of solid phase materials: styrene-divinylbenzene copolymer and graphitized carbon black, with acetone and methanol used as desorption solvents, respectively.
  • The method demonstrated good performance with recovery rates between 73% and 111% and limits of detection ranging from 0.2 to 28 ng/l, and it was successfully tested on various ground water samples.

Article Abstract

A method for the determination of 5 triazine herbicides and 12 degradation products in environmental water samples using liquid chromatography-electrospray ionization mass spectrometry (LC/ESI/MS) has been developed. The pesticides in water were extracted with two types of solid phase: a styrene-divinylbenzene copolymer and a graphitized carbon black. Desorption solvents for the extracted compounds were acetone for the styrene-divinylbenzene copolymer and methanol for the graphitized carbon black. Overall recoveries from ground water and river water ranged from 73% to 111%. The limits of detection (LODs) were 0.2 to 28 ng l(-1). This method was applied to several ground water samples.

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Source
http://dx.doi.org/10.2116/analsci.20.227DOI Listing

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