AI Article Synopsis
- - Hydrophobic vitamin B(12) was attached to a platinum electrode, enabling it to serve as a catalyst.
- - This setup demonstrated a redox couple between Co(ii) and Co(i), meaning it can switch between two states.
- - Under visible light, the Co(i) reacts with phenethyl bromide, successfully producing styrene with an impressive turnover number over 6000 in just 1 hour.
Article Abstract
Hydrophobic vitamin B(12) was covalently immobilized onto a platinum electrode surface, and the immobilized complex exhibits Co(ii)/Co(i) redox couple and in situ the Co(i) species reacts with phenethyl bromide to form styrene under irradiation with visible light with a turnover number of over 6000 for 1 h.
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| http://dx.doi.org/10.1039/b309457j | DOI Listing |
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