A new chiral binaphthyl-strapped iron-porphyrin 4 b that exhibits unprecedented catalytic activity toward the enantioselective epoxidation of terminal olefins was synthesized. Typical enantiomeric excesses (ee) of 90 % were measured with a maximum of 97 % for the epoxidation of styrene, whereas the turnover numbers (TON) averaged 16000.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.200305222 | DOI Listing |
Publication Analysis
Top Keywords
enantioselective epoxidation
8
epoxidation terminal
8
terminal olefins
8
unique binaphthyl
4
binaphthyl strapped
4
strapped iron-porphyrin
4
iron-porphyrin catalyst
4
catalyst enantioselective
4
olefins chiral
4
chiral binaphthyl-strapped
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!