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Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides. | LitMetric
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Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides.

David M Hodgson Timothy J Buxton Iain D Cameron Emmanuel Gras Eirene H M Kirton

Org Biomol Chem

Dyson Perrins Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK OX1 3QY.

Published: December 2003

Enantioselective alpha-deprotonation of achiral epoxides 1, 21, and 26 using organolithiums in the presence of (-)-sparteine 2 and subsequent electrophile trapping gives access to enantioenriched trisubstituted epoxides 9-17, 22, 23, 27 and 28 (in up to 86% ee).

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 Source
http://dx.doi.org/10.1039/b309717jDOI Listing

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