Zeolite-promoted oxidations of 1,1-diarylethylenes.

Org Lett

Chemistry Department, Department 3838, 1000 East University Avenue, University of Wyoming, Laramie, WY 82071, USA.

Published: December 2003

The intrazeolite photooxygenations of four diarylethylenes have been examined. Several intermediates, including an epoxide, have been identified by comparison to independently synthesized samples. Aldehyde intermediates were shown to undergo intrazeolite Norrish type I cleavages in competition with a novel new photooxygenation/autoxidation reaction. [reaction: see text]

Download full-text PDF

Source
http://dx.doi.org/10.1021/ol035927tDOI Listing

Publication Analysis

Top Keywords

zeolite-promoted oxidations
4
oxidations 11-diarylethylenes
4
11-diarylethylenes intrazeolite
4
intrazeolite photooxygenations
4
photooxygenations diarylethylenes
4
diarylethylenes examined
4
examined intermediates
4
intermediates including
4
including epoxide
4
epoxide identified
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!