It is probably redundant to stress how extensive are nowadays the attempts to reduce the diesel particulate emissions from automotive and stationary sources. The present paper looks into a technology relied on a catalytic trap based on a SiC wall-flow monolith lined with suitable catalysts for the sake of promoting a more complete and faster regeneration after particulate capture. All the major steps of the catalytic filter preparation are dealt with, including: the synthesis and choice of the proper catalyst and trap materials, the development of an in situ catalyst deposition technique, the bench testing of the derived catalytic wall-flow. The best catalyst selected was the perovskite La0.9K0.1Cr0.9O3-delta. The filtration efficiency and the pressure drop of the catalytic and non-catalytic monoliths were evaluated on a diesel engine bench under various operating conditions.
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Environ Sci Technol
January 2025
School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084, PR China.
Vehicle nitrogen oxides (NO) significantly increase nitrogen dioxide (NO) exposure in traffic-related environments. The NO/NO ratios are crucial for accurate NO modeling and are closely linked to public health concerns. In 2020, we used a mobile platform to follow test trucks (plume-chasing) that were installed with a portable emission measuring system (PEMS) on two restricted driving tracts.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Center for Environmental Research and Technology (CE-CERT), Bourns College of Engineering, University of California, 1084 Columbia Avenue, Riverside, California 92507, United States.
We assessed the real-world particulate emissions of a goods movement diesel vehicle, with an emphasis on total particle number and solid particle number emissions at different cutoff sizes. The vehicle was tested on routes in the South Coast Air Basin (SCAB) of California, representative of typical goods movement operation between the ports to warehouses and logistic centers with a mixture of urban and highway driving, as well as elevation change. We evaluated emissions during normal vehicle operation and diesel particulate filter (DPF) active regeneration events.
View Article and Find Full Text PDFPLoS One
December 2024
Department of Chemistry, American University of Beirut, Beirut, Lebanon.
Lebanon, plagued by political and economic crises, experienced a government collapse in early 2020, leading to an electrical nationwide blackout by 2023. Diesel generators were used to compensate for the absence of power production from the national provider, Electricité du Liban (EDL). To investigate the effect of the crisis on the levels of 16 EPA particle bound polycyclic aromatic hydrocarbons (PPAHs), an annual comparative analysis of three locations within Beirut started in 2022 and ended in 2023.
View Article and Find Full Text PDFSci Rep
December 2024
Centro de Investigación en Materiales Avanzados S.C. (CIMAV-Mty), Unidad Monterrey, Alianza Norte 202, Apodaca, N.L., C.P. 66628, Mexico.
This research investigates the concentrations, sources, and health risks of polycyclic aromatic hydrocarbons (PAHs) and nitrated PAHs (NPAHs) in particulate matter with an aerodynamic diameter of 10 μm or less (PM[Formula: see text]) from critical urban centers in northern Mexico: Metropolitan Monterrey Area (MMA), Chihuahua (CHI), and Ciudad Juárez (CDJ). Advanced gas chromatography-mass spectrometry (GC-MS and GC-NCI-MS) revealed significant PAHs concentrations, with levels in MMA reaching 108.89 ± 99.
View Article and Find Full Text PDFSci Rep
December 2024
Clean Energy Technologies Research Institute (CETRI), Process Systems Engineering, Faculty of Engineering & Applied Science, University of Regina, 3737 Wascana Parkway, Regina, SK, S4S 0A2, Canada.
Real-world emissions of particulate matter (PM) and smoke opacity were studied for an older-model diesel pickup truck during four types of driving tests, namely fixed-point test, snap-acceleration test, road test, and hill road test (uphill/downhill). A portable emissions measurement system (PEMS) and an opacimeter were used to measure real-time concentrations of PM and smoke opacity, respectively, and simultaneously. Correlation analysis showed a significant positive association between PM and opacity, suggesting the feasibility of using an opacimeter to estimate PM mass emissions from diesel vehicles.
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