A versatile synthesis of new pyrimidinyl nitronyl nitroxides.

Chem Commun (Camb)

Département de Recherche Fondamentale sur la Matiére Condensée, Service de Chimie Inorganique et Biologique, (UMR CNRS 5046), 17 Rue des Martyrs F38054, Grenoble Cedex 09, France.

Published: November 2003

Pyrimidinyl nitronyl nitroxides where the bis-N-oxy fragment is included in a six-membered ring were prepared from diacetonamine by a sequence of reactions including a Grignard reaction, a Ritter reaction and oxidation of the intermediate pyrimidine; the properties of the 2-phenyl-substituted representative are fully described.

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Source
http://dx.doi.org/10.1039/b309786bDOI Listing

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