Efficient tools for on-line and in situ monitoring of environmental pollutants are required to provide early warning systems. In addition, such tools can contribute important information on the progress of various remediation treatments. One of the recently developed monitoring technologies involves the use of whole-cell biosensors. Such biosensors could be constructed to detect general toxicity or specific toxicity caused by one or more pollutants. Currently, a large spectrum of microbial biosensors have been developed that enable the monitoring of pollutants by measuring light, fluorescence, color or electric current. Electrochemical monitoring is of special interest for in situ measurements as it can be performed using simple, compact and mobile equipment and is easily adaptable for on-line measurements. Here we survey the potential application of electrochemical biosensors in monitoring of general toxicity as well as hydrocarbons and heavy metals.
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http://dx.doi.org/10.1016/j.biotechadv.2003.08.014 | DOI Listing |
J Am Chem Soc
January 2025
Department of Chemical Engineering, Stanford University, 443 Via Ortega, Stanford, California 94305, United States.
A significant challenge in commercializing electrochemical CO reduction (COR) is achieving catalyst durability. In this study, online inductively coupled mass spectrometry (ICP-MS) was used to investigate catalyst degradation via nanoparticle detachment and/or dissolution into metal ions under COR operating conditions in 0.1 M KHCO.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, PR China. Electronic address:
Catalytic oxidation of formaldehyde (HCHO) is a highly effective method for indoor HCHO removal. However, many aspects of the catalytic mechanism remain unclear, making the optimization of catalysts largely empirical. Herein, we report a coupled experimental and computational study of Pt/TiO catalysts, with special focus on the functional roles of surface oxygen vacancies and hydroxyl groups in the catalytic oxidation of HCHO.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia.
In situ measurements of the chemical identity and quantity of anode gases during electrochemical measurements and rare earth (RE) electrolysis from fluoride-based molten salts composed of different kinds of rare earth oxides (REOs) were performed using FTIR spectrometry. Linear sweep voltammetry (LSV) was carried out to characterize oxidation processes and determine the anodic effect from NdF + PrF + LiF + REO melt. RE complex formation and subsequent reactions on the GC anode surface were discussed to understand the formation pathways of CO/CO and perfluorocarbon gases (PFC), mainly CF and CF.
View Article and Find Full Text PDFReact Chem Eng
January 2025
Center for Sustainable Catalysis and Engineering (CSCE), KU Leuven 3001 Leuven Belgium
Most conventional zeolite synthesis takes place in closed batch autoclaves that cannot be monitored or controlled during the process. Moreover, the study of time-dependent parameters of the synthesis with the conventional "cooling-opening" procedure not only reduces accuracy as a series of reactors (never 100% identical) needs to be started in parallel (and stopped at different times), it is also labor intense. Furthermore, the classic batch concept does not permit the intermediate addition of species without disrupting synthesis and the cooling-reheating effects.
View Article and Find Full Text PDFMikrochim Acta
November 2024
School of Chemistry, Sun Yat-Sen University, Guangzhou, 510006, China.
Gold-grafted melamine sponge (AuSp) was fabricated and applied as surface-enhanced Raman spectroscopy (SERS) substrate for enzyme-linked immunoassay of 2 typical mycotoxins, zearalenone (ZEN) and T-2 toxin. The gold nanoparticles were in situ grown on the sponge, and the product showed good effect in enhancing Raman signal and good stability. COMSOL and Gaussian simulations were used to analyze the enhancing effect.
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