We report the first organic light-emitting field-effect transistor. The device structure comprises interdigitated gold source and drain electrodes on a Si/SiO(2) substrate. A polycrystalline tetracene thin film is vacuum sublimated on the substrate forming the active layer of the device. Both holes and electrons are injected from the gold contacts into this layer leading to electroluminescence from the tetracene. The output characteristics, transfer characteristics, and the optical emission properties of the device are reported. A possible mechanism for electron injection is suggested.
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http://dx.doi.org/10.1103/PhysRevLett.91.157406 | DOI Listing |
Small Methods
January 2025
Wide-bandgap semiconductors (WBGS) with energy bandgaps larger than 3.4 eV for GaN and 3.2 eV for SiC have gained attention for their superior electrical and thermal properties, which enable high-power, high-frequency, and harsh-environment devices beyond the capabilities of conventional semiconductors.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Departamento de Química, Instituto Tecnológico de Aeronáutica, São José dos Campos, 12228-900 São Paulo, Brazil.
Polycyclic aromatic hydrocarbons (PAHs) exhibit intriguing characteristics that position them as promising candidates for advancements in organic semiconductor technologies. Notably, tetracene finds substantial utility in Electronics due to its application in organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs). The strategic introduction of an isoelectronic boron-nitrogen (B,N) pair to replace a carbon-carbon pair in acenes introduces changes in the electronic structure, allowing for the controlled modulation of diradical characteristics.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Graduate School of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, Chiba 263-8522, Japan.
Organic multilayer systems, which are stacked layers of different organic materials, are used in various organic electronic devices such as organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs). In particular, OFETs are promising as key components in flexible electronic devices. In this study, we investigated how the inclusion of an insulating tetratetracontane (TTC) interlayer in ambipolar indigo-based OFETs can be used to alter the crystallinity and electrical properties of the indigo charge transport layer.
View Article and Find Full Text PDFACS Omega
December 2024
Department of Applied Chemistry, School of Science and Technology, Meiji University, 1-1-1 Higashi-Mita, Tama-ku, Kawasaki, Kanagawa 214-8571, Japan.
Organic semiconductors have been widely studied owing to their potential applications in various devices, such as field-effect transistors, light-emitting diodes, solar cells, and image sensors. However, they have a limitation of significantly lower carrier mobility compared to silicon, which is a widely used inorganic semiconductor. Therefore, to address such limitations, these molecules should be further explored.
View Article and Find Full Text PDFAcc Chem Res
December 2024
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.
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