In the structures of the title compounds, [Pd(C(5)H(9))(C(32)H(37)N(2)O(2)P)]PF(6) and [PdCl(2)(C(32)H(37)N(2)O(2)P)], the bis(dihydrooxazolyl)phosphine ligand is N,P-bidentate, with S chirality on the P atom. In the allyl complex, the pi-allyl ligand ligates in a syn-syn-kappa(3)C manner.

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http://dx.doi.org/10.1107/s010827010302170xDOI Listing

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