We report the unprecedented redox-triggered on/off coordination of a bridgehead nitrogen donor in an iron complex of the tripodal ligand 2,2',2''-nitrilotribenzoate; the complex is an efficient redox catalyst for H2O2 oxidation of hydroquinone while complexes of related ligands are inactive.
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http://dx.doi.org/10.1039/b307277k | DOI Listing |
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