Multiresidue method for the determination of pesticides in Korean domestic crops by gas chromatography/mass selective detection.

The multiresidue method used in this study allows the determination of 101 pesticides, including organophosphorus, organochlorine, and nitrogen-containing pesticides, in crops by gas chromatography with mass selective detector. Analysis was performed in the selected-ion monitoring mode, and the identities of the positive analytes were confirmed by retention time and the ratios of selected ions. The selected ion mode demonstrated an acceptable selectivity for most of the pesticides determined in 3 kinds of samples (Chrysanthemum coronarium; Perilla japonica, leaf; and Lactuca savita, which are very popular vegetables eaten raw in Korea), and very minor interferences were observed in the elution area of the pesticide analytes. Samples were spiked with pesticides at 0.1-1.0 mg/kg. The recoveries of 90% of the pesticides were between 70 and 110%; however, the recoveries of acephate and folpet were very poor, i.e., < 50%. The limits of detection (LODs) for most pesticides were between 0.02 and 0.3 mg/kg, and the LODs for about half of the pesticeds studied were < 0.05 mg/kg.