[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.

Chem Commun (Camb)

Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QR.

Published: September 2003

The bimetallic complex [V(Cp)]2Pn, containing a V-V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

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Source
http://dx.doi.org/10.1039/b306688fDOI Listing

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