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Identifying the Activated Carbon Electrode Aging Pathways in Lithium-Ion Hybrid Capacitors.
ACS Appl Energy Mater
January 2025
Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Berdychowo 4, 60-965 Poznan, Poland.
This paper reports on several mechanisms of carbon aging in a hybrid lithium-ion capacitor operating with 1 mol L LiPF in an ethylene carbonate/dimethyl carbonate 1:1 vol/vol electrolyte. Carbon electrodes were subjected to a constant polarization protocol (i.e.
View Article and Find Full Text PDFN-Alkylation of 1,2,3-Triazoles with Ethers under Thermodynamical Control.
Org Lett
January 2025
School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
Herein, a relay strategy incorporating oxidative cross dehydrogenative coupling (CDC) and N- to N-isomerization is disclosed for the formal N-selective alkylation of triazoles with ethers under thermodynamic control conditions. By taking advantage of the different thermodynamical stabilities of N- and N-alkylated triazoles (3.65 kcal/mol), the initially formed N-isomers can be converted into their more stable N-isomers when reaching thermodynamic equilibrium.
View Article and Find Full Text PDFEffect of polishing on the morphology of Zircaloy-4 nanostructure: formation of a novel hexagonal nanoscale pattern.
RSC Adv
January 2025
Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro, Yuseong-gu Daejeon 34141 Republic of Korea
Zircaloy-4 (Zr-4) is widely used as the cladding material in nuclear power plants (NPPs) due to its excellent corrosion resistance and low neutron absorption cross-section. Under Loss of Coolant Accident (LOCA) conditions, oxidation of Zr-4 can compromise the safety of the NPPs by accelerating hydrogen production. Therefore, enhancing the oxidation resistance of Zr-4 is a critical research focus.
View Article and Find Full Text PDFUtilization of Chlorella vulgaris methyl ester blend with diethyl ether to mitigate emissions of an unaltered single cylinder ci engine.
Environ Sci Pollut Res Int
January 2025
Engine Testing Laboratory, Department of Automobile Engineering, College of Engineering and Technology, SRM Institute of Science and Technology, Kattankulathur, 603203, Tamil Nadu, India.
The present work emphasizes the viability of methyl ester production, characterization, and utilization of third-generation biofuel from Chlorella vulgaris microalgae. The presence of methyl oleate (CHO) in the Chlorella vulgaris methyl ester (CVME) algae signifies the existence of higher oxidation stability and prone to peroxidation. The single-stage transesterified CVME algae contains majorly (C-H) functional group trailed by (C = O), (C-O), (O-CH), (C-O-C) with the elemental compositions of 66.
View Article and Find Full Text PDFChemical Profiling, Antioxidant, and Antiproliferative Activities of Algerian Cistus creticus L. Leaf Extracts: Evidence from In vitro and In Silico Studies.
Curr Top Med Chem
January 2025
Medicinal Chemistry Department, Theodor Bilharz Research Institute Kornaish El Nile, Warrak El-Hadar, Imbaba (P.O. 30), Giza 12411, Egypt.
Background: Research into oxidative stress, cancer, and natural products revealed promising avenues for therapeutic intervention. Natural products are considered potent pharmaceuticals in combating oxidative stress and its relationship with cancer.
Methods: This study was carried out to evaluate the chemical profile and antioxidant activities using DPPH, ABTS, Phenanthroline, Cupric, Phosphomolybdenum, FRAP, Hydroxyl, Iron chelation in vitro assays, and anticancer properties by MTT method of Cistus creticus extracts.
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