A symmetry X system that has been constructed for the absolute measurements of reflectance and transmittance of specular samples in the infrared region is described. The system has been designed so that it can be incorporated into commercial Fourier-transform infrared spectrometers. Although ten mirrors were used in this system, it is disclosed that the geometric mean of two reflectance values is independent of the reflectance difference of the individual mirrors and the optical loss at each mirror. This system achieves spectral measurements with high accuracy and within a short period of time. In particular, the system affords us the self-diagnostic ability for measured spectra, and the simultaneous measurements of reflectance and transmittance under the same geometry enable us to evaluate measurement uncertainties. Although the symmetry X system is used for infrared spectral measurements, the measurement method, design principles, and features are generally applicable to other wavelengths as well.
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http://dx.doi.org/10.1364/ao.42.005064 | DOI Listing |
ACS Nano
January 2025
Sauvage Laboratory for Smart Materials, School of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China.
With the potential to surpass the Shockley-Queisser (S-Q) limitation for solar energy conversion, the bulk photovoltaic (BPV) effect, which is induced by the broken inversion symmetry of the lattice, presents prospects for future light-harvesting technologies. However, the development of BPV is largely limited by the low solar spectrum conversion efficiency of existing noncentrosymmetric materials with wide band gaps. This study reports that the strain-induced reduction of inversion symmetry can enhance the second-order nonlinear susceptibility (χ) of SnPSe crystals by an order of magnitude, which contributes to an extremely high value of 1.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Physics, Indian Institute of Technology Banaras Hindu University, Indian Institute of Technology (Banaras Hindu University), Department of Physics, Varanasi, Varanasi, Uttar Pradesh, 221005, INDIA.
In the present work, we reinvestigate the atomic ordering of a Pb-free Morphotropic Phase Boundary (MPB) composition viz., K0.5Na0.
View Article and Find Full Text PDFRep Prog Phys
January 2025
School of Electrical Engineering, Xi'an Jiaotong University, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, CHINA.
Parity-time symmetry is a fundamental concept in non-Hermitian physics that has recently gained attention for its potential in engineering advanced electronic systems and achieving robust wireless power transfer even in the presence of disturbances, through the incorporation of nonlinearity. However, the current parity-time-symmetric scheme falls short of achieving the theoretical maximum efficiency of wireless power transfer and faces challenges when applied to non-resistive loads. In this study, we propose a theoretical framework and provide experimental evidence demonstrating that asymmetric resonance, based on dispersive gain, can greatly enhance the efficiency of wireless power transfer beyond the limits of symmetric approaches.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Shanghai Institute of Organic Chemistry, Materials Science, 345 lingling Road, 200032, Shanghai, CHINA.
Three-dimensional covalent organic frameworks (3D COFs), a class of highly porous crystalline polymers, have exhibited great potentials in many applications. However, the reported topologies of 3D COFs have been limited to high-symmetry crystal systems, which significantly hindered the development of such functional materials. Herein, we demonstrate the first construction of four highly crystalline orthorhombic 3D COFs with an unprecedented fmj topology, based on judiciously choosing rotatable monomers.
View Article and Find Full Text PDFChem Sci
December 2024
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Zhongshan Road 457 Dalian 116023 China
In solid-state NMR, dipolar-based heteronuclear polarization transfer has been extensively used for sensitivity enhancement and multidimensional correlations, but its efficiency often suffers from undesired spin interactions and hardware limitations. Herein, we propose a novel dipolar-echo edited R-symmetry (DEER) sequence, which is further incorporated into the INEPT-type scheme, dubbed DEER-INEPT, for achieving highly efficient heteronuclear polarization transfer. Numerical simulations and NMR experiments demonstrate that DEER-INEPT offers significantly improved robustness, enabling efficient polarization transfer under a wide range of MAS conditions, from slow to ultrafast rates, outperforming existing methods.
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