Purpose: The possibility of polymerizing glass fiber-reinforced composite (FRC) material into the root canal was preliminarily evaluated by determining the depth of light-initiated polymerization of FRC.
Materials And Methods: The material used was polymer-preimpregnated E-glass fiber reinforcement, which was further impregnated with light-polymerizable dimethacrylate monomer resin. The same resin without fiber reinforcement was used as a control. Six different lengths (range 4 to 24 mm) of light-protected cylinders filled with the test materials were light polymerized from one end. The degree of monomer conversion was determined from the other end by FT-IR spectrometry. Infrared spectra were recorded at six time points from the beginning of polymerization. The microhardness of the test materials was measured from the light-exposure surface toward the other end of the cylinder.
Results: Both groups showed a reduction in the degree of conversion with increased lengths of the cylinder. The FRC group showed a higher degree of conversion in the longest sample group compared to the resin group. Microhardness measurement confirmed the constant reduction of the degree of conversion by the reduced Vickers hardness values with increased cylinder length of the FRC.
Conclusion: Generally, the glass FRC showed an almost equal degree of conversion after light curing as monomer resin without fibers. However, in the longest cylinders, FRC showed a slightly higher degree of conversion compared to resin only; this might be due to the fibers' ability to conduct light.
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Food Chem X
January 2025
College of Food Science & Engineering, Qingdao Agricultural University, Qingdao 266109, China.
This study aimed to evaluate the effects of dietary inulin (0-30 g/kg) on duck meat, muscle fiber types, meat quality, antioxidant ability, Low-field nuclear magnetic resonance, amino acid and off-flavor. These results indicated that inulin promoted the conversion of type II to type I muscle fibers. Compared with the control group, supplementation with 20 g/kg inulin reduced ( < 0.
View Article and Find Full Text PDFJ Dent
January 2025
University of Saskatchewan, College of Dentistry. 107 Wiggins Rd, Saskatoon, SK, Canada. S7N 5E5. Electronic address:
Bulk-fill, monochromatic, and ORMOCER composites were introduced in restorative dentistry with the aim of reducing clinical time and/or alleviating contraction stresses at the interface between the tooth and restoration. While the conversion and immediate properties of these materials are comparable to conventional composites, studies evaluating their long-term properties and the structure of the polymer matrix are lacking. The objective of this study was to evaluate the degree of conversion and, indirectly, the crosslink density of conventional, bulk-fill, monochromatic, and ORMOCER resin composites.
View Article and Find Full Text PDFACS Nano
January 2025
Conte Center for Polymer Research, Polymer Science and Engineering, University of Massachusetts Amherst, Amherst, Massachusetts 01003, United States.
Bottlebrush block copolymers (BBCPs) are a unique class of materials that contain a backbone with densely grafted and chemically distinct polymeric side chains. The nonlinear architecture of BBCPs provides numerous degrees of freedom in their preparation, including control over key parameters such as grafting density, side chain length, block arrangement, and overall molecular weight. This uniquely branched structure provides BBCPs with several important distinctions from their linear counterparts, including sterically induced side chain and backbone conformations, rapid and large self-assembled nanostructures, and reduced or eliminated entanglement effects (assuming sufficient grafting density and that the molecular weight of the side chains is below their respective entanglement molecular weight).
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, Hong Kong.
Lead-free halide double perovskites provide a promising solution for the long-standing issues of lead-containing halide perovskites, i.e., the toxicity of Pb and the low stability under ambient conditions and high-intensity illumination.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Operative Dentistry, Faculty of Dentistry, Chulalongkorn University, 34 Henri Dunant Road, Pathumwan, Bangkok, 10330, Thailand.
To evaluate the effect of sulfinate salt on the bond performance of a two-step self-etch adhesive to an intracoronally bleached pulpal dentin surface. Intracoronally bleached bovine teeth were treated with or without sulfinate salt (sulfinate agent (SA): Clearfil DC activator) before 2-SEA (Clearfil SE Bond 2) application, while unbleached teeth served as the control (n = 5 teeth). Microtensile bond strength (µTBS) using the bonded surface area of 1 mm at the crosshead speed of 1 mm/min measurements after 24 h storage and thermocycles (TC), degree of conversion (DC) analyses by Raman spectroscopy (n = 3 teeth), ultrastructure of resin-dentin interface (n = 3 teeth), and intracoronally bleached pulp chamber dentin surface (n = 3 teeth) observations by scanning electron microscopy (SEM) were subsequently performed.
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