By using the method of solid phase synthesis, a series of samples of KYbxGd(1 - x) (WO4)2 with different Yb3+ mole fraction of x = 0.03, 0.08, 0.10, 0.12, 0.15, 0.18, 0.20, 0.25, 0.28, respectively were synthesized when they were heated at 1,000 degrees C. Their fluorescence spectra were measured by using LD with a wavelength of 980 nm as the pumping source and RF-540 fluorescence spectrum measurement device. The weak fluorescence at 1,020 nm and strong blue fluorescence at 476 nm were obtained. Also, the relationship between the Yb3+ doping mole fraction and the fluorescence intensity at 476 nm was measured. The result indicates that the intensity of blue fluorescence increases rapidly with the increase of Yb3+ doping mole fraction and reaches the highest point at the Yb3+ doping mole fraction of 25%, then drops quickly with the increase of Yb3+ doping mole fraction. The result also indicates that the fluorescence intensity at 1,020 nm reaches the highest point when the Yb3+ doping mole fraction is about 8%-10%.
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Molecules
December 2024
Coimbra Chemistry Center, Institute of Molecular Sciences (CQC-IMS), University of Coimbra, 3004-535 Coimbra, Portugal.
The membrane dipole potential that arises from the interfacial water and constitutive dipolar groups of lipid molecules modulates the interaction of amphiphiles and proteins with membranes. Consequently, its determination for lipid mixtures resembling the existing diversity in biological membranes is very relevant. In this work, the dipole potentials of monolayers, formed at the air-water interface, from pure or mixed lipids (1-palmitoyl-2-oleoyl--glycero-3-phosphocholine (POPC), 1-palmitoyl-2-oleoyl--glycero-3-phosphoethanolamine (POPE), 1-palmitoyl-2-oleoyl--glycero-3-phosphatidyserine (POPS), sphingomyelin (SpM) and cholesterol) were measured and correlated with the mean area per lipid.
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December 2024
Bioinformatics Analysis Team, Research Core Center, Research Institute, National Cancer Center, Goyang 10408, Gyeonggi-do, Republic of Korea.
The cost-effectiveness of whole exome sequencing (WES) remains controversial due to variant call variability, necessitating sensitivity and specificity evaluation. WES was performed by three companies (AA, BB, and CC) using reference standards composed of DNA from hydatidiform mole and individual blood at various ratios. Sensitivity was assessed by the detection rate of null-homozygote (N-H) alleles at expected variant allelic fractions, while false positive (FP) errors were counted for unexpected alleles.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Pharmaceutics, College of Pharmacy, King Khalid University, Abha 62529, Saudi Arabia.
The production of fine particles by green technology like supercritical carbon dioxide requires the assessment of substantial solubility data at high pressures. This study represents the first determination of the solubility of methyldopa in carbon dioxide at pressures and temperatures ranging from 12 to 30 MPa and from 313.2 to 343.
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January 2025
Environmental Science & Engineering, Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Boston, MA 02134.
Wastewater receives per- and polyfluoroalkyl substances (PFAS) from diverse consumer and industrial sources, and discharges are known to be a concern for drinking water quality. The PFAS family includes thousands of potential chemical structures containing organofluorine moieties. Exposures to a few well-studied PFAS, mainly perfluoroalkyl acids (PFAA), have been associated with increased risk of many adverse health outcomes, prompting federal drinking water regulations for six compounds in 2024.
View Article and Find Full Text PDFJ Oleo Sci
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Center of Excellence for Advanced Materials Research, King Abdulaziz University.
In the present study, the mixed micellization behavior of gemini surfactant-1, 5-bis (N-hexadecyl- N, N-dimethylammonium) pentane dibromide (G5) with non-ionic surfactant triton X-100 (TX-100) was investigated in the micellar phase by utilizing the conductometric technique. The deviation of ideal critical micelle concentration (cmc*) from experimental critical micelle concentration (cmc) has been estimated using well-known Clint's theory of mixed micelles. The regular solution approximation was used to determine the interaction parameter (β) and found to be negative.
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