An improved method for the synthesis of dolichyl H-phosphonate was developed using 2-chloro-4H-1,3,2-benzodioxaphosphorin-4-one (salicyl chlorophosphite) as a reagent. Dolichyl phosphorofluoridate was for the first time synthesized from dolichyl H-phosphonate by its treatment with chlorotrimethylsilane, oxidation with iodine, and subsequent interaction with fluoride ion in pyridine.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1023/a:1024909519917 | DOI Listing |
Publication Analysis
Top Keywords
synthesis dolichyl
8
dolichyl h-phosphonate
8
dolichyl fluorophosphate]
4
fluorophosphate] improved
4
improved method
4
method synthesis
4
h-phosphonate developed
4
developed 2-chloro-4h-132-benzodioxaphosphorin-4-one
4
2-chloro-4h-132-benzodioxaphosphorin-4-one salicyl
4
salicyl chlorophosphite
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!