Electrospray mass spectrometry of 2-aminotroponimines and 2-aminotropones.

Eur J Mass Spectrom (Chichester)

Departamento de Química Orgánica y Biología, Facultad de Ciencias, UNED, Senda del Rey 9, E-28040 Madrid, Spain.

Published: March 2004

A series of aminotroponimine and aminotropone derivatives were studied by electrospray mass spectrometry. MS and MS/MS data were acquired according to automated procedures. In the case of mono- and di-halogenated compounds, their specific behavior upon collisionally-activated dissociation conditions provided rapid structural assignments through inexpensive isotopic labeling MS/MS experiments.

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http://dx.doi.org/10.1255/ejms.560DOI Listing

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