The characteristics of ultraviolet spectra of five alpha,alpha'-dioxoketene cyclis,s,s-acetals (N,N-acetals) have been studied in different solvent, on the basis of last paper. And the character of ultraviolet spectra of sulfur-containing compounds and nitrogen-containing compound was compared in the same solvent, the changing rules with the change of chemical structure have been indicated. It is specially important that the character of such as this conjugated system was studied, however it almost did not do before. And the this can used in studies afterwards.
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Sci Rep
January 2025
Department of Information Technology, College of Computers and Information Technology, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia.
We proposed the ultrawideband solar absorber using the multisized metal resonator oriented on the top of the multilayered Metal-SiO₂-MXene-MgF₂-Tungsten structure. We have carried out a numerical investigation of this structure for the 100-2500 THz frequency, which covers the infrared, visible, and UV spectra. The proposed solar absorber is numerically investigated for the different physical parameters, such as the height of the layers, unit cell size, and resonator orientation, to identify optimized results for the high absorption capacity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen Ø, DK-2100, Denmark. Electronic address:
We have recorded the gas phase spectrum of isoprene at room temperature from the mid-infrared range and into the visible range (600 cm to 17050 cm). Absorption spectra were obtained by Fourier transform infrared, conventional dispersion ultraviolet-visible-near-infrared and cavity ring-down spectroscopy to cover the entire range with a resolution comparable to that of the instruments on the James Webb Space Telescope. We have assigned the CH-stretching fundamental and overtone bands corresponding to the Δv=1-6 transitions based on anharmonic vibrational calculations using normal mode and local mode models, for the lower- and higher-energy regions, respectively.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
When dielectrics are hit with intense infrared (IR) laser pulses, transient metalization can occur. The initial attosecond dynamics behind this metallization are not entirely understood. Therefore, simulations are needed to understand this process and to help interpret experimental observations of it, such as with attosecond transient absorption (ATA).
View Article and Find Full Text PDFResearch (Wash D C)
January 2024
School of Resources and Environment, Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China.
Solar-driven CO photoreduction holds promise for sustainable fuel and chemical productions, but the complex proton-coupled multi-electron transfer processes and sluggish oxidation half-reaction kinetics substantially hinder its efficiency. Here, we devised a rational catalyst design to address these challenges by fabricating ferrocene carboxylic acid-functionalized CsSbBr nanocrystals (CSB-Fc NCs), which facilitate simultaneous benzyl alcohol oxidation and CO reduction reactions under visible-light irradiation. The synchronized proton-coupled electron transfer processes between the reduction and oxidation half-reactions on CSB-Fc NCs resulted in a 5-fold increase in the CO reduction rate (45.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012 China. Electronic address:
The line list is essential for accurately modeling various astrophysical phenomena, such as stellar photospheres and atmospheres of extrasolar planets. This paper introduces a new line database for the PS molecule spanning from the ultraviolet to the infrared regions, covering wavenumbers up to 45000 cm and containing over ten million transitions between 150,458 states with total angular momentum J < 160. Accurate line intensities for rotational, vibrational and electronic transitions are generated by using the general purpose variational code DUO.
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