Linear and nonlinear optical properties of ZnGeP2 crystal for infrared laser device applications: revisited.

Measurement of refractive indices in the spectral bands 9-11 microm and 1.32 microm from a cw CO2 laser and a Q-switched Nd:YAG laser, respectively, is reported in a ZnGeP2 crystal. A new set of Sellmeier dispersion relations has been derived from the measured refractive indices data in this crystal. Second-harmonic generation (SHG) of CO2 laser radiation in this crystal is also reported. It is also seen that the previously reported phase-matching data for others experiments in SHG and optical parametric devices is explained satisfactorily with this new set of Sellmeier dispersion relation.