The temperature-dependent decay dynamics of innershell holes in CsBr was measured by using high harmonics. The measured lifetime was as short as 1.5 ps at 340 K due to increasing the Auger-allowed final state density in the Urbach exciton tail, whereas it is 1.1 ns at 10 K, determined by radiative recombination. The temperature-dependent Auger lifetime extrapolated to a high temperature corresponds to the fully energy-allowed Auger decay. In the model to be presented, this yields an interatomic Auger decay lifetime of 2.4+3.8/-1.5 fs, in line with a theoretical calculation for NaF.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.91.017401 | DOI Listing |
Phys Chem Chem Phys
December 2024
Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.
We present an theoretical method to calculate the resonant Auger spectrum in the presence of ultrafast dissociation. The method is demonstrated by deriving the L-VV resonant Auger spectrum mediated by the 2pσ* resonance in HCl, where the electronic Auger decay and nuclear dissociation occur on the same time scale. The Auger decay rates are calculated within the one-center approximation and are shown to vary significantly with the inter-nuclear distance.
View Article and Find Full Text PDFMol Pharm
December 2024
Princess Margaret Cancer Centre, University Health Network, Toronto M5G 1L7, Canada.
Thallium-201 is an Auger electron-emitting radionuclide with significant potential for targeted molecular radiotherapy of cancer. It stands out among other Auger electron emitters by releasing approximately 37 Auger and Coster-Kronig electrons per decay, which is one of the highest numbers in its category. It has also a convenient half-life of 73 h, a stable daughter product, established production methods, and demonstrated high radiotoxicity.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Laboratoire d'Optique Appliquée, ENSTA Paris, CNRS, Ecole Polytechnique, Institut Polytechnique de Paris, 91761 Palaiseau, France.
In this article, we study electron dynamics in HgTe quantum dots with a 1.9 μm gap, a material relevant for infrared sensing and emission, using ultrafast spectroscopy with 35 fs time resolution. Experiments have been carried out at several probing photon energies around the gap, which allows us to follow the relaxation path of the photoexcited electrons.
View Article and Find Full Text PDFAdv Mater
December 2024
Dipartimento di Scienza dei Materiali, Università degli Studi di Milano-Bicocca, Via R. Cozzi 55, Milano, 20125, Italy.
The recent emergence of quantum-confined nanomaterials in the field of radiation detection, in particular lead halide perovskite nanocrystals, offers scalability and performance advantages over conventional materials. This development raises fundamental questions about the mechanism of scintillation itself at the nanoscale and the role of particle size, arguably the most defining parameter of quantum dots. Understanding this is crucial for the design and optimization of future nanotechnology scintillators.
View Article and Find Full Text PDFNanomaterials (Basel)
October 2024
Department of Physics, Institute of Physics, Budapest University of Technology and Economics, Műegyetem Rkp. 3., H-1111 Budapest, Hungary.
The measurement and description of the charge-carrier lifetime (τc) is crucial for the wide-ranging applications of lead-halide perovskites. We present time-resolved microwave-detected photoconductivity decay (TRMCD) measurements and a detailed analysis of the possible recombination mechanisms including trap-assisted, radiative, and Auger recombination. We prove that performing injection-dependent measurement is crucial in identifying the recombination mechanism.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!