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Beta-elimination of a phosphonate group from an alkoxy radical: an intramolecular acylation approach using an acylphosphonate as a carbonyl group acceptor. | LitMetric
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Beta-elimination of a phosphonate group from an alkoxy radical: an intramolecular acylation approach using an acylphosphonate as a carbonyl group acceptor.

Sunggak Kim Chang Ho Cho Chae Jo Lim

J Am Chem Soc

Center for Molecular Design and Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea.

Published: August 2003

On the basis of facile beta-elimination of a phosphonate group from an alkoxy radical, intramolecular acylation reaction has been developed, in which an acylphosphonate is used as an excellent carbonyl group radical acceptor.

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http://dx.doi.org/10.1021/ja036499pDOI Listing

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