Three new glycosphingolipids with a cis-Delta(17)-fatty acyl moiety, namely, catacerebrosides A-C (1-3), along with two known glycosphingolipids, cerebrosides B and D, six known ergostane-type sterols, and tyrosamine were isolated from the fungus Catathelasma ventricosa. The structures of 1-3 were elucidated on the basis of spectroscopic analysis and chemical methods.
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