The first examples of ring-closing olefin metathesis of vinyl chlorides.

Org Lett

Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.

Published: July 2003

[reaction: see text] Ring-closing metathesis (RCM) of olefinic vinyl chlorides can be effected by using the second generation Grubbs catalyst (10 mol %, PhH, 65 degrees C) to produce a variety of carbocyclic and heterocyclic five-, six-, and seven-membered rings in excellent yields.

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http://dx.doi.org/10.1021/ol034775zDOI Listing

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