The detailed shape of the dense material network of inverse opals has a significant influence on the appearance of band gaps in these photonic crystals. One example of these topologically very similar networks is the skeleton structure, which can show two complete band gaps. Like all inverse opals, these structures are self-standing and can be fabricated via self-assembly strategies. The first step for obtaining these novel kind of photonic crystals has been achieved by synthesizing a titania skeleton structure.
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http://dx.doi.org/10.1002/cphc.200200531 | DOI Listing |
Sci Adv
January 2025
Department of Mechanical Engineering, University of California, Berkeley, CA 94720, USA.
A metamaterial absorber capable of swiftly altering its electromagnetic response in the microwave range offers adaptability to changing environments, such as tunable stealth capabilities. Inspired by the chameleon's ability to change color through the structural transformation of photonic lattice crystals, which shift the bandgaps of reflection and transmission of visible light, we designed a crisscross structure that transforms from an expanded to a collapsed form. This transformation enables a switch between broadband absorption and peak transmission in the microwave range (4 to 18 gigahertz).
View Article and Find Full Text PDFLangmuir
January 2025
Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe, Mizuho, Nagoya 467-8603, Aichi, Japan.
In this study, we demonstrate a novel and efficient fabrication methodology for nonclose-packed, two-dimensional (2D) colloidal crystals exhibiting square lattice structures. In our recent work, we detailed the formation of 2D colloidal crystals via the electrostatic adsorption of three-dimensional (3D) charged colloidal crystals onto oppositely charged substrates. These 3D colloidal crystals possessed a face-centered cubic (FCC) lattice structure with their (111) planes aligned parallel to the substrate, facilitating the formation of 2D crystals with triangular lattice arrangements upon adsorption.
View Article and Find Full Text PDFInorg Chem
January 2025
Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan.
Sodium borohydride dihydrate (NaBH·2HO) forms through dihydrogen bonding between the hydridic hydrogen of the BH ion and the protonic hydrogen of the water molecule. High-pressure structural changes in NaBH·2HO, observed up to 11 GPa through X-ray diffraction and Raman scattering spectroscopy, were analyzed to assess the influence of dihydrogen bonds on its crystal structure. At approximately 4.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.
Van der Waals (vdWs) materials are promising candidates for hetero-integration with silicon photonics toward miniaturization and integration. VdWs materials like molybdenum telluride and black phosphorus, despite being prominent, exhibit air sensitivity, and their room temperature emissions can be significantly broadened by tens of meV. Here, a self-encapsulation strategy is developed to scalably synthesize robust 2D vdWs ErOCl with sub-meV narrow emissions at the telecom C-band.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics and Astronomy, Seoul National University, Seoul 08826, Korea.
Atomic defects in solids offer a versatile basis to study and realize quantum phenomena and information science in various integrated systems. All-electrical pumping of single defects to create quantum light emission has been realized in several platforms including color centers in diamond and silicon carbide, which could lead to the circuit network of electrically triggered single-photon sources. However, a wide conduction channel which reduces the carrier injection per defect site has been a major obstacle.
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