The pseudotetrahedral, formally 5-coordinate complex [Ni(eta 3-CH2C(CH3)CH2)(SbPh3)3][BAr'4] (Ar' = 3,5-C6H3(CF3)2) as well as the 4-coordinate derivative [Ni(eta 3-CH2C(CH3)CH2)(AsPh3)2][BAr'4] act as extremely efficient catalysts for the oligomerization of styrene.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b302553e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
[Ni(eta 3-CH2C(CH3)CH2)(SbPh3)3][BAr'4]: an extremely active cationic allyl nickel-stibine catalyst for the oligomerization of styrene.
Chem Commun (Camb)
May 2003
Departamento de Ciencia de Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Apartado 40, 11510 Puerto Real, Cádiz, Spain.
The pseudotetrahedral, formally 5-coordinate complex [Ni(eta 3-CH2C(CH3)CH2)(SbPh3)3][BAr'4] (Ar' = 3,5-C6H3(CF3)2) as well as the 4-coordinate derivative [Ni(eta 3-CH2C(CH3)CH2)(AsPh3)2][BAr'4] act as extremely efficient catalysts for the oligomerization of styrene.
View Article and Find Full Text PDFeta 6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization.
Chem Commun (Camb)
January 2003
Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, cl Américo Vespucio s/n, Isla de la Cartuja, 41092 Sevilla, Spain.
A simple procedure for the preparation of cationic arene complexes of Ni(II) of composition [Ni(eta 6-ArX)(eta 3-C3H5)]+[BAr'4]- (X = OH, H) is reported. These compounds are shown to behave as highly active catalysts for the polymerization of 1,3-butadiene and styrene.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!