The dinuclear complex [Rh2I2(mu-CPh2)2(mu-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and PiPr3 from a terminal into a bridging site is also described.
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| http://dx.doi.org/10.1039/b301251d | DOI Listing |
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