Z-selectivity was observed for iodohydroxylation of Se-substituted allenes with I2 and H2O, which is opposite to that of 1,2-allenyl sulfoxides. With n-hexane as the co-solvent Z-iodoamination leading to N-(3-organoseleno-2-iodo-2(Z)-propenyl)acetamide was observed. A brief rational for the stereoselectivity of this reaction is provided.
Download full-text PDF |
Source |
|---|
Publication Analysis
Top Keywords
se-substituted allenes
8
highly regio-
4
regio- stereoselective
4
stereoselective four-component
4
four-component iodoamination
4
iodoamination se-substituted
4
allenes efficient
4
efficient synthesis
4
synthesis n-3-organoseleno-2-iodo-2z-propenyl
4
n-3-organoseleno-2-iodo-2z-propenyl acetamides
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!