In the title compound, [Ba(C(7)H(5)O(2)S)(2)(H(2)O)(4)](n), the Ba(II) atom lies on a mirror plane and is nine-coordinated by four bridging carboxylate O atoms of the thiosalicylate ligands, two bridging water molecules and three terminal water molecules. There is an intramolecular S-H.O hydrogen bond between the S and O atoms in the thiosalicylate ligand. A one-dimensional coordination polymer is formed via weak metal-metal interactions along polymeric zigzag chains.
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| http://dx.doi.org/10.1107/s010827010300667x | DOI Listing |
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