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A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system. | LitMetric
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A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system.

Hajime Kawanami Akiyoshi Sasaki Keitaro Matsui Yutaka Ikushima

Chem Commun (Camb)

Supercritical Fluid Research Center, National Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino-ku, Sendai 983-8551, Japan.

Published: April 2003

The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.

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 Source
http://dx.doi.org/10.1039/b212823cDOI Listing

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