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Asymmetric reductive ring-opening of bicyclic olefins catalyzed by palladium and nickel complexes. | LitMetric
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Asymmetric reductive ring-opening of bicyclic olefins catalyzed by palladium and nickel complexes.

Lih-Ping Li Dinesh Kumar Rayabarapu Malay Nandi Chien-Hong Cheng

Org Lett

Department of Chemistry, Tsing Hua University, Hsinchu, Taiwan 300.

Published: May 2003

[reaction: see text] Asymmetric reductive ring opening of oxa- and azabenzonorbornadienes with organic acids and zinc powder under mild conditions catalyzed by Ni(binap)Cl(2) or Pd(binap)I(2) produces the corresponding 1,2-dihydronaphth-1-ols in good to excellent yields with high enantioselectivity.

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 Source
http://dx.doi.org/10.1021/ol034251zDOI Listing

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