Over five years, we have compared the hyperfine frequencies of 133Cs and 87Rb atoms in their electronic ground state using several laser-cooled 133Cs and 87Rb atomic fountains with an accuracy of approximately 10(-15). These measurements set a stringent upper bound to a possible fractional time variation of the ratio between the two frequencies: d/dt ln([(nu(Rb))/(nu(Cs))]=(0.2+/-7.0)x 10(-16) yr(-1) (1sigma uncertainty). The same limit applies to a possible variation of the quantity (mu(Rb)/mu(Cs))alpha(-0.44), which involves the ratio of nuclear magnetic moments and the fine structure constant.
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http://dx.doi.org/10.1103/PhysRevLett.90.150801 | DOI Listing |
J Chem Phys
April 2023
Department of Physics, Princeton University, Princeton, New Jersey 08544, USA.
Measurements of the 0-0 hyperfine resonant frequencies of ground-state Rb atoms show a nonlinear dependence on the pressure of the buffer gases Ar, Kr, and Xe. The nonlinearities are similar to those previously observed with Rb and Cs and presumed to come from alkali-metal-noble-gas van der Waals molecules. However, the shape of the nonlinearity observed for Xe conflicts with previous theory, and the nonlinearities for Ar and Kr disagree with the expected isotopic scaling of previous Rb results.
View Article and Find Full Text PDFRSC Adv
June 2021
MRTechnology TCI-B5, Sengen Tsukuba 305-0047 Japan.
The dynamic behavior of alkali metal ions, Li, Na, K, Rb and Cs in aqueous solutions is one of the most important topics in solution chemistry. Since these alkali metals contain nuclear magnetic resonance (NMR) active nuclei, it is possible to directly measure the diffusion constants of the alkali metal ions using the pulsed field gradient (PFG) NMR method. In this paper, the Li, Na, Rb, Cs and H resonances are observed for diffusion constants in aqueous solution and the solvent HO.
View Article and Find Full Text PDFWe present a parameter set for obtaining the maximum number of atoms in a grating magneto-optical trap (gMOT) by employing a machine learning algorithm. In the multi-dimensional parameter space, which imposes a challenge for global optimization, the atom number is efficiently modeled via Bayesian optimization with the evaluation of the trap performance given by a Monte-Carlo simulation. Modeling gMOTs for six representative atomic species - Li, Na, Rb, Sr, Cs, Yb - allows us to discover that the optimal grating reflectivity is consistently higher than a simple estimation based on balanced optical molasses.
View Article and Find Full Text PDFNat Rev Chem
September 2021
Laboratory of Magnetic Resonance, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland.
Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe atomic-level microstructure and structural dynamics in metal halide perovskites. It can be used to measure dopant incorporation, phase segregation, halide mixing, decomposition pathways, passivation mechanisms, short-range and long-range dynamics, and other local properties. This Review describes practical aspects of recording solid-state NMR data on halide perovskites and how these afford unique insights into new compositions, dopants and passivation agents.
View Article and Find Full Text PDFJ Am Chem Soc
November 2020
Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1-5, Zurich CH-8093, Switzerland.
Two- and three-dimensional lead-halide perovskite (LHP) materials are novel semiconductors that have generated broad interest owing to their outstanding optical and electronic properties. Characterization and understanding of their atomic structure and structure-property relationships are often nontrivial as a result of the vast structural and compositional tunability of LHPs as well as the enhanced structure dynamics as compared with oxide perovskites or more conventional semiconductors. Nuclear magnetic resonance (NMR) spectroscopy contributes to this thrust through its unique capability of sampling chemical bonding element-specifically (H, C, N, Cl, K, Br, Rb, I, Cs, and Pb nuclei) and locally and shedding light onto the connectivity, geometry, topology, and dynamics of bonding.
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