Role of rigidity in the fluid-solid transition.

Phys Rev Lett

Instituto de Fisica, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000, Distrito Federal, Mexico.

Published: April 2003

We examine the fluid-solid transition for a hard-disk system. By counting the near neighbors in the average configurations of a grand-canonical Monte Carlo simulation, this enables us to relate the thermodynamic transition with the rigidity theory, since we find that the coordination number in the fluid-solid transition is close to the coordination number predicted by a mean field rigidity theory, due to dynamical jamming of particles, where the contact region between disks is the radial ring outside a disk with a maximum allowed coordination number that is not bigger than six. Using these ideas, we were able to produce a continuous glass-like transition when nucleation of rigidity is suppressed.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevLett.90.145701DOI Listing

Publication Analysis

Top Keywords

fluid-solid transition
12
coordination number
12
rigidity theory
8
transition
5
role rigidity
4
rigidity fluid-solid
4
transition examine
4
examine fluid-solid
4
transition hard-disk
4
hard-disk system
4

Similar Publications

We calculate the shear relaxation times in four important simple monatomic model fluids: Lennard-Jones, Yukawa, soft-sphere, and hard-sphere fluids. It is observed that in properly reduced units, the shear relaxation times exhibit quasiuniversal behavior when the density increases from the gaslike low values to the high-density regime near crystallization. They first decrease with density at low densities, reach minima at moderate densities, and then increase toward the freezing point.

View Article and Find Full Text PDF

The Effect of Wettability on Confinement-Induced Phase Behavior and Storage of Alkane in Nanoporous Media.

Langmuir

November 2024

Center of Innovation for Flow through Porous Media, Department of Energy and Petroleum Engineering, University of Wyoming, Laramie, Wyoming 82071, United States.

The impact of wettability on the confined phase behavior of fluids is paramount for various applications, such as gas storage, carbon dioxide sequestration, and water purification. However, the understanding of the fluid-solid intermolecular interactions in confined systems is still limited and requires further investigation. This work investigates the effect of hydrophilic and hydrophobic nanoporous materials on the adsorption and desorption isotherms of -butane.

View Article and Find Full Text PDF

Lake ecological processes and nutrient patterns are increasingly affected by water level variation around the world. Still, the long-term effects of water level change on lake ecosystems and their implications for suitable lake level management have rarely been studied. Here, we studied the ecosystem dynamics of a mesotrophic lake located in the cold and arid region of northern China based on long-term paleo-diatom and fishery records.

View Article and Find Full Text PDF

Latent thermal energy storage (LTES) devices can efficiently store renewable energy in thermal form and guarantee a stable-temperature thermal energy supply. The gravity-driven motion melting (GDMM) process improves the overall melting rate for packaged phase-change material (PCM) by constructing an enhanced flow field in the liquid phase. However, due to the complex mechanisms involved in fluid-solid coupling and liquid-solid phase transition, numerical simulation studies that demonstrate physical details are necessary.

View Article and Find Full Text PDF

Low-k nano-dielectrics facilitate electric-field induced phase transition in high-k ferroelectric polymers for sustainable electrocaloric refrigeration.

Nat Commun

January 2024

State Key Laboratory of Mechanical System and Vibration, Interdisciplinary Research Center, Institute of Refrigeration and Cryogenics, and MOE Key Laboratory for Power Machinery and Engineering, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.

Ferroelectric polymer-based electrocaloric effect may lead to sustainable heat pumps and refrigeration owing to the large electrocaloric-induced entropy changes, flexible, lightweight and zero-global warming potential. Herein, low-k nanodiamonds are served as extrinsic dielectric fillers to fabricate polymeric nanocomposites for electrocaloric refrigeration. As low-k nanofillers are naturally polar-inactive, hence they have been widely applied for consolidate electrical stability in dielectrics.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!