We report neutron scattering studies on two single crystal samples of the electron-doped (n-type) superconducting (SC) cuprate Nd2-xCexCuO4 (x=0.15) with T(c)=18 and 25 K. Unlike the hole-doped (p-type) SC cuprates, where incommensurate magnetic fluctuations commonly exist, the n-type cuprate shows commensurate magnetic fluctuations at the tetragonal (1/2 1/2 0) reciprocal points both in the SC and in the normal state. A spin gap opens up when the n-type cuprate becomes SC, as in the optimally doped p-type La2-xSrxCuO4. The gap energy, however, increases gradually up to about 4 meV as T decreases from T(c) to 2 K, which contrasts with the spin pseudogap behavior with a T-independent gap energy in the SC state of p-type cuprates.
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Science
August 2024
Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA.
In the underdoped n-type cuprate NdCeCuO, long-range antiferromagnetic order reconstructs the Fermi surface, resulting in a putative antiferromagnetic metal with small Fermi pockets. Using angle-resolved photoemission spectroscopy, we observe an anomalous energy gap, an order of magnitude smaller than the antiferromagnetic gap, in a wide portion of the underdoped regime and smoothly connecting to the superconducting gap at optimal doping. After considering all the known ordering tendencies in tandem with the phase diagram, we hypothesize that the normal-state gap in the underdoped n-type cuprates originates from Cooper pairing.
View Article and Find Full Text PDFPhys Chem Chem Phys
October 2020
Center of New Technologies, University of Warsaw, Zwirki i Wigury 93, 02-089 Warsaw, Poland.
AgF2 is a layered material and a correlated charge transfer insulator with an electronic structure very similar to the parent compounds of cuprate high-TC superconductors. It is also interesting as it is a powerful oxidizer. Here we present a first principles computation of its electronic properties in a slab geometry including its work function for the (010) surface (7.
View Article and Find Full Text PDFAdv Mater
April 2020
Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Strontium titanate (SrTiO or STO) is important for oxide-based electronics as it serves as a standard substrate for a wide range of high-temperature superconducting cuprates, colossal magnetoresistive manganites, and multiferroics. Moreover, in its heterostructures with different materials, STO exhibits a broad spectrum of important physics such as superconductivity, magnetism, the quantum Hall effect, giant thermoelectric effect, and colossal ionic conductivity, most of which emerge in a two-dimensional (2D) electron gas (2DEG) formed at an STO interface. However, little is known about its counterpart system, a 2D hole gas (2DHG) at the STO interface.
View Article and Find Full Text PDFScience
January 2015
Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada. Quantum Matter Institute, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada.
In cuprate high-temperature superconductors, an antiferromagnetic Mott insulating state can be destabilized toward unconventional superconductivity by either hole or electron doping. In hole-doped (p-type) cuprates, a charge ordering (CO) instability competes with superconductivity inside the pseudogap state. We report resonant x-ray scattering measurements that demonstrate the presence of charge ordering in the n-type cuprate Nd(2-x)Ce(x)CuO4 near optimal doping.
View Article and Find Full Text PDFPhys Rev Lett
April 2009
Max-Planck-Institut für Physik komplexer Systeme, Nöthnitzer Strasse 38, 01187 Dresden, Germany.
State-of-the-art quantum chemical methods are applied to the study of the multiorbital correlated electronic structure of a Fe-As compound, the recently discovered LiFeAs. Our calculations predict a high-spin, S=2, ground-state configuration for the Fe ions, which shows that the on-site Coulomb interactions are substantial. Also, orbital degeneracy in the (xz, yz) sector and a three-quarter filling of these levels suggest the presence of strong fluctuations and are compatible with a low metallic conductivity in the normal state.
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