The title compound, [Pd(C(6)N(4))(C(18)H(15)P)(2)].0.7CH(2)Cl(2), shows a planar coordination geometry around the metal atom that is an almost perfect isosceles triangle if the tetracyanoethene (tcne) ligand is deemed to occupy a single coordination site. The framework of the tcne ligand shows small distortions due to intramolecular steric contacts between the C[triple-bond]N groups and phenyl rings of the triphenylphosphine ligands.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1107/s010827010300458x | DOI Listing |
Publication Analysis
Top Keywords
tcne ligand
8
eta2-tetracyanoethenebistriphenylphosphine-kappappalladium-dichloromethane 1/07
4
1/07 title
4
title compound
4
compound [pdc6n4c18h15p2]07ch2cl2
4
[pdc6n4c18h15p2]07ch2cl2 planar
4
planar coordination
4
coordination geometry
4
geometry metal
4
metal atom
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!