An unprecedented trans-oriented product from the cleavage of a dipeptide.

Chem Commun (Camb)

Department of Chemistry, University of Houston, Houston, Texas 77204-5641, USA.

Published: March 2003

An unusual trans cleavage reaction was observed when trans-[Co(3,2,3-tet)Cl2]Cl (3,2,3-tet = N,N'-bis(3-aminopropyl)ethylenediamine), was allowed to react with beta-alanyl-L-histidine (a bioactive dipeptide) in an aqueous medium at pH approximately 7.5 and 45 degrees C for 6 h.

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http://dx.doi.org/10.1039/b212587kDOI Listing

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