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RIFM fragrance ingredient safety assessment, d,l-menthone 1,2-glycerol ketal, CAS Registry Number 63187-91-7.
Food Chem Toxicol
July 2024
Member Expert Panel for Fragrance Safety, The Journal of Dermatological Science (JDS), Department of Dermatology, Hamamatsu University School of Medicine, 1-20-1 Handayama, Higashi-ku, Hamamatsu, 431-3192, Japan.
Discovery and biochemical characterization of thermostable glycerol oxidases.
Appl Microbiol Biotechnol
December 2024
Molecular Enzymology, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands.
Alditol oxidases are promising tools for the biocatalytic oxidation of glycerol to more valuable chemicals. By integrating in silico bioprospecting with cell-free protein synthesis and activity screening, an effective pipeline was developed to rapidly identify enzymes that are active on glycerol. Three thermostable alditol oxidases from Actinobacteria Bacterium, Streptomyces thermoviolaceus, and Thermostaphylospora chromogena active on glycerol were discovered.
View Article and Find Full Text PDFSubstrate recognition mode of a glycoside hydrolase family 42 β-galactosidase from subspecies (Bga42A) revealed by crystallographic and mutational analyses.
Microbiome Res Rep
May 2023
Graduate School of Biostudies, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
subsp. uses a glycoside hydrolase (GH) family 42 β-galactosidase (Bga42A) for hydrolyzing lacto--tetraose (LNT), which is the most abundant core structure of human milk oligosaccharides (HMOs). As such, Bga42A represents one of the pivotal enzymes underpinning the symbiosis between bifidobacteria and breastfed infants.
View Article and Find Full Text PDFDefining the Conformational Ensembles Associated with Ligand Binding to Cyclooxygenase-2.
Biochemistry
November 2023
Department of Structural Biology, Jacobs School of Medicine and Biomedical Sciences, University of Buffalo, the State University of New York, Buffalo, New York 14203, United States.
Cyclooxygenases (COX) catalyze the committed step in the production of prostaglandins responsible for the maintenance of physiological homeostasis. While crystal structures of COX in complex with substrates and inhibitors have provided insight into the molecular interactions governing their binding, they have not uncovered specific details related to the protein conformational motions responsible for important aspects of the COX function. We created a cysteine-free COX-2 construct and introduced a free cysteine at position-122 to enable labeling with 3-bromo-1,1,1-trifluoroacetone (BTFA).
View Article and Find Full Text PDFSynthesis and Fungicide Activity on of Glycerol Derivatives Bearing 1,2,3-Triazole Fragments.
J Agric Food Chem
May 2023
Departamento de Química e Física, Grupo de Pesquisa de Estudos Aplicados em Produtos Naturais e Síntese Orgânica (GEAPS), Universidade Federal Do Espírito Santo, Alto Universitário, Alegre 29500-000, Espírito Santo State, Brazil.
In agriculture, the control of fungal infections is essential to improve crop quality and productivity. This study describes the preparation and fungicidal activity evaluation of 12 glycerol derivatives bearing 1,2,3-triazole fragments. The derivatives were prepared from glycerol in four steps.
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