AI Article Synopsis
- Aryl chiral auxiliaries are more effective than alkyl chiral auxiliaries in asymmetric photoreactions.
- This effectiveness is due to the presence of cation-pi interactions.
- Cation-pi interactions enhance the stability and reactivity of the aryl auxiliaries in these reactions.
Article Abstract
Owing to the existence of cation-pi interactions, aryl chiral auxiliaries perform far better than alkyl chiral auxiliaries during asymmetric photoreaction.
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| http://dx.doi.org/10.1039/b209810e | DOI Listing |
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