In the title compound, the coordination around the Cu atom is a distorted square-pyramid involving three N atoms from the ligand and one N atom from the azido group at the basal plane. The Cl atom is located at the apical position. The Cu atom is 0.32(5)A above the basal plane. There are three intramolecular and four weak intermolecular hydrogen bonds in the structure. IR spectra confirm the asymmetric N3 stretching vibrations of the terminal azide group.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.2116/analsci.19.335 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Chemical corrosion resistance mechanism of titanium alloy radiation rods with self-protected structure.
Ultrason Sonochem
January 2025
State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Central South University, Changsha 410083, China; Light Alloy Research Institute, Central South University, Changsha 410083, China.
The chemical corrosion of the TC4 radiation rod surface (TRRS) during the ultrasonic casting process has the potential to significantly impair the smooth conduction of ultrasonic waves. However, in the later stages of corrosion, a self-protected structure (TSPS) emerges under the ultrasonic cavitation effect, which serves to impede the chemical corrosion of the TRRS and markedly reduce the rate of mass loss of the radiation rod. This ensures the smooth ultrasonic conduction of the radiation rod during operation.
View Article and Find Full Text PDFAn efficient electrocatalytic in-situ hydrogen peroxide generation for ballast water treatment with oxygen groups.
Sci Total Environ
January 2025
Ability R&D Energy Research Centre, School of Energy and Environment, City University of Hong Kong, Hong Kong; State Key Laboratory of Marine Pollution, City University of Hong Kong, Hong Kong.
The in-situ electrochemical production of hydrogen peroxide (HO) offers a promising approach for ballast water treatment. However, further advancements are required to develop electrocatalysts capable of achieving efficient HO generation in seawater environments. Herein, we synthesized two-dimensional lamellated porous carbon nanosheets enriched with oxygen functional groups, which exhibited exceptional performance in HO electrosynthesis.
View Article and Find Full Text PDFAtomic Gap-State Engineering of MoS for Alkaline Water and Seawater Splitting.
ACS Nano
January 2025
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
Transition-metal dichalcogenides (TMDs), such as molybdenum disulfide (MoS), have emerged as a generation of nonprecious catalysts for the hydrogen evolution reaction (HER), largely due to their theoretical hydrogen adsorption energy close to that of platinum. However, efforts to activate the basal planes of TMDs have primarily centered around strategies such as introducing numerous atomic vacancies, creating vacancy-heteroatom complexes, or applying significant strain, especially for acidic media. These approaches, while potentially effective, present substantial challenges in practical large-scale deployment.
View Article and Find Full Text PDFMesoporous Co-MoS with sulfur vacancies: A bifunctional electrocatalyst for enhanced water-splitting reactions in alkaline media.
J Colloid Interface Sci
January 2025
School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 China.
As a graphene-like layered material, molybdenum disulfide (MoS), has attracted increasing attentions for its promising application in electrocatalysis. Whereas MoS still suffers from the sluggish reaction kinetics in oxygen evolution reaction (OER) due to the low density of active sites in most exposed planes. In this work, high density of active sites on MoS basal planes has been obtained by synthesizing mesoporous MoS with Co doping and sulfur vacancies (V).
View Article and Find Full Text PDFThe Prognostic Value of Right Ventricular End-Diastolic Basal Diameter Index by Echocardiography in Connective Tissue Diseases Associated With Pulmonary Artery Hypertension.
Int J Rheum Dis
January 2025
Department of Rheumatology, The First Affiliated Hospital of Nanjing Medical University, Nanjing, China.
Background: Right ventricular (RV) failure is a well-recognized pivotal prognostic factor of adverse outcomes in pulmonary artery hypertension (PAH), while RV dilation provides significant implications for adaptive or maladaptive changes. PAH is a predominant cause of mortality among patients with connective tissue disease (CTD). This study aims to elucidate the prognostic significance of RV morphology, as assessed by echocardiography (ECHO), in with CTD associated with PAH (CTD-PAH).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!