[formula: see text] Treatment of vinyl-substituted [2.2.1]- and [2.2.2]-bicyclocarbinols with NaOCl and AcOH provides [3.2.1]- and [3.2.2]-beta-chloro-bicycloketones, respectively. For [2.2.2]-bicycles, these chlorinative ring expansions are particularly efficient and selective.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ol0267331 | DOI Listing |
Publication Analysis
Top Keywords
chlorinative ring
8
bleach/acetic acid-promoted
4
acid-promoted chlorinative
4
ring expansion
4
expansion [221]-
4
[221]- [222]-bicycles
4
[222]-bicycles [formula
4
[formula text]
4
text] treatment
4
treatment vinyl-substituted
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!