We study the nonconserved coarsening kinetics of a reconstructed semiconductor surface. The domain size evolution is obtained in situ by time-resolved surface x-ray diffraction. The system exhibits four equivalent domain types with two nonequivalent types of domain boundaries. Small domains are prepared by molecular beam epitaxy deposition of one GaAs layer. We find the correlation lengths of the domain size distribution to depend on time as l is proportional to t(0.42+/-0.05) in the half-order reflections and l is proportional to t(0.22+/-0.05) in the quarter-order reflections. The fraction of the higher energy domain boundaries increases as lnt.
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http://dx.doi.org/10.1103/PhysRevLett.90.016101 | DOI Listing |
Langmuir
December 2024
Department of Chemical Engineering, University of California, Santa Barbara, Santa Barbara, California 93106, United States.
The mammalian cell membrane is embedded with biomolecular condensates of protein and lipid clusters, which interact with an underlying viscoelastic cytoskeleton network to organize the cell surface and mechanically interact with the extracellular environment. However, the mechanical and thermodynamic interplay between the viscoelastic network and liquid-liquid phase separation of 2-dimensional (2D) lipid condensates remains poorly understood. Here, we engineer materials composed of 2D lipid membrane condensates embedded within a thin viscoelastic actin network.
View Article and Find Full Text PDFSoft Matter
December 2024
Centre for Condensed Matter Theory, Indian Institute of Science, Bangalore, Karnataka, India.
Chem Sci
December 2024
College of Physics, Weihai Innovation Research Institute, College of Materials Science and Engineering, Qingdao University Qingdao 266071 China
J Chem Phys
November 2024
Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544, USA.
In a companion paper, we put forth a thermodynamic model for complex formation via a chemical reaction involving multiple macromolecular species, which may subsequently undergo liquid-liquid phase separation and a further transition into a gel-like state. In the present work, we formulate a thermodynamically consistent kinetic framework to study the interplay between phase separation, chemical reaction, and aging in spatially inhomogeneous macromolecular mixtures. A numerical algorithm is also proposed to simulate domain growth from collisions of liquid and gel domains via passive Brownian motion in both two and three spatial dimensions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, North Third Ring Road 15, Chaoyang District, Beijing 100029, P. R. China.
BiS has attracted increasing attention in sodium-ion batteries (SIBs) for its high theoretical capacity and low discharge platform. However, the sodium storage performance of BiS is limited by poor electrical conductivity and volume expansion during cycling. Herein, we report a special polypyrrole (PPy)-coated MoS/BiS (MBS@PPy) heterostructure composite obtained by hydrothermal reaction as an anode material for SIB.
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