As is well known, the extrusion rate of polymers from a cylindrical tube or slit (a "die") is in practice limited by the appearance of "melt fracture" instabilities which give rise to unwanted distortions or even fracture of the extrudate. We present the results of a weakly nonlinear analysis which gives evidence for an intrinsic generic route to melt fracture via a weakly nonlinear subcritical instability of viscoelastic Poiseuille flow. This instability and the onset of associated melt fracture phenomena appear at a well-defined ratio of the elastic stresses to viscous stresses of the polymer solution.
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http://dx.doi.org/10.1103/PhysRevLett.90.024502 | DOI Listing |
Heliyon
December 2024
Department of Mechanics, Electrical Power and Computer, Science and Research Branch, Islamic Azad University, Tehran, Iran.
ACS Appl Mater Interfaces
December 2024
Department of Aerospace Engineering, Iowa State University, Ames, Iowa 50014, United States.
Using an interatomic potential that can capture the tetrahedral configuration of water molecules (HO) in ice without the need to explicitly track the motion of the O and H atoms, coarse-grained (CG) atomistic simulations are performed here to characterize the structures, energy, cohesive strengths, and fracture resistance of the grain boundaries (GBs) in polycrystalline ice resulting from water freezing. Taking the symmetric tilt grain boundaries (STGBs) with a tilting axis of ⟨0001⟩ as an example, several main findings from our simulations are (i) the GB energy, , exhibits a strong dependence on the GB misorientation angle, θ. The classical Read-Shockley model only predicts the - θ relation reasonably well when θ < 20° or θ > 45° but fails when 20° < θ < 45°; (ii) two "valleys" appear in the -θ landscape.
View Article and Find Full Text PDFPLoS One
December 2024
School of Architecture and Civil Engineering, Xi'an University of Science and Technology, Xi'an, China.
Understanding he impact of dry-wet and freeze-thaw cycles on the mechanical properties of unloaded damaged rock masses in reservoir bank slopes is crucial for revealing the deformation and failure mechanisms in artificially excavated slope rock masses within fluctuation zones. To address, the study focuses on unloaded damaged samples subjected to excavation disturbances, conducting various cycles of dry-wet and freeze-thaw treatment along with uniaxial and triaxial re-loading tests. A damage statistical constitutive model was established based on the experimental results and validated using numerical simulation methods.
View Article and Find Full Text PDFPolymers (Basel)
November 2024
Department of Vehicle Engineering, WuFeng University, Chia-Yi 621303, Taiwan.
The bone plates used in surgery to assist in fracture healing are often manufactured by metal injection molding (MIM) using a feedstock material consisting of metal powder and polymer binder. However, if the local powder concentration is too low or uneven, black lines may be formed, which impair the product appearance. Furthermore, if the melding temperature is too low, it can lead to meld lines and reduced mechanical properties.
View Article and Find Full Text PDFCarbohydr Polym
February 2025
School of Chemistry and Materials Science, Ludong University, Key Laboratory of High Performance and Functional Polymer in the Universities of Shandong Province, Collaborative Innovation Center of Shandong Province for High Performance Fibers and Their Composites, Yantai 264025, China.
Antifreeze proteins (AFPs) are a type of protein capable of inhibiting ice crystal growth, lowering the freezing point, and protecting organisms from cold-induced damage. In this study, cellulose nanocrystals (CNCs) are chemically modified to enhance the hydrogel's performance. The synergistic effect with AFPs further regulates its mechanical properties, antifreeze performance, and high sensing sensitivity.
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